Unit 7: Electrochemistry

  1. What does the “i” represent in the van ‘t Hoff equation for osmotic pressure?
    • A) Current
    • B) Ideal gas constant
    • C) Number of particles formed in solution
    • D) Temperature
    • Answer: C) Number of particles formed in solution
  2. What is the primary cause of polarization in an electrolytic cell?
    • A) Overvoltage
    • B) Low current
    • C) High temperature
    • D) Low concentration of electrolyte
    • Answer: A) Overvoltage
  3. In a concentration cell, what causes the cell potential to develop?
    • A) Different electrode materials
    • B) Different electrode potentials
    • C) Different ion concentrations in the electrolyte
    • D) Different temperatures of the solutions
    • Answer: C) Different ion concentrations in the electrolyte
  4. What is the Nernst equation used to determine in electrochemical cells?
    • A) Standard cell potential
    • B) Reaction rate
    • C) Cell potential under non-standard conditions
    • D) Heat of reaction
    • Answer: C) Cell potential under non-standard conditions
  5. Which of the following is a correct statement about the Gibbs free energy change (ΔG) and the cell potential (E) of an electrochemical cell?
    • A) ΔG = -nFE
    • B) ΔG = nFE
    • C) ΔG = -FE
    • D) ΔG = nF/E
    • Answer: A) ΔG = -nFE
  6. The quantity of electricity required to deposit one mole of a substance is called:
    • A) Faraday constant
    • B) Equivalent weight
    • C) Faraday’s constant
    • D) Molar mass
    • Answer: A) Faraday constant
  7. What is the effect of increasing the concentration of the electrolyte on the conductivity of the solution?
    • A) Conductivity decreases
    • B) Conductivity remains constant
    • C) Conductivity increases
    • D) Conductivity fluctuates
    • Answer: C) Conductivity increases
  8. What is the Faraday constant approximately equal to?
    • A) 96485 C/mol
    • B) 96500 C/mol
    • C) 100000 C/mol
    • D) 50000 C/mol
    • Answer: A) 96485 C/mol
  9. Which type of reaction does the galvanic cell facilitate?
    • A) Endothermic reaction
    • B) Exothermic reaction
    • C) Spontaneous redox reaction
    • D) Non-spontaneous redox reaction
    • Answer: C) Spontaneous redox reaction
  10. What happens to the cell potential of an electrochemical cell if the temperature is increased?
    • A) It decreases
    • B) It remains constant
    • C) It increases
    • D) It becomes zero
    • Answer: C) It increases

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