11. The Law of Mass Action states that:

  • A) Rate of a reaction depends on temperature only
  • B) Rate of reaction depends on concentration of reactants
  • C) Rate of reaction depends on pressure
  • D) Equilibrium constant is unaffected by concentration
  • Answer: B

12. In a reversible chemical reaction at equilibrium, the rate of the forward reaction is:

  • A) Zero
  • B) Greater than the reverse reaction
  • C) Less than the reverse reaction
  • D) Equal to the reverse reaction
  • Answer: D

13. Which of the following expressions represents the equilibrium constant (Kc) for the reaction ( aA + bB \rightleftharpoons cC + dD )?

  • A) ( K_c = \frac{[A]^a[B]^b}{[C]^c[D]^d} )
  • B) ( K_c = \frac{[C]^c[D]^d}{[A]^a[B]^b} )
  • C) ( K_c = [A][B] – [C][D] )
  • D) ( K_c = [C][D] \times [A][B] )
  • Answer: B

14. If the equilibrium constant (Kc) for a reaction is very large, it indicates that:

  • A) The reactants are favored at equilibrium
  • B) The reaction hardly proceeds
  • C) Products are favored at equilibrium
  • D) The reaction has no equilibrium
  • Answer: C

15. At equilibrium, the concentration of reactants and products:

  • A) Continues to change
  • B) Becomes zero
  • C) Remains constant
  • D) Becomes equal
  • Answer: C

16. The units of an equilibrium constant (Kc) for a reaction are:

  • A) Always in M
  • B) Always in mol/L
  • C) Depend on the balanced equation
  • D) Always unitless
  • Answer: C

17. In the reaction ( N_2 + 3H_2 \rightleftharpoons 2NH_3 ), the expression for ( K_c ) is:

  • A) ( K_c = \frac{[NH_3]}{[N_2][H_2]^3} )
  • B) ( K_c = \frac{[N_2][H_2]^3}{[NH_3]^2} )
  • C) ( K_c = \frac{[NH_3]^2}{[N_2][H_2]^3} )
  • D) ( K_c = [N_2][H_2]^3 \times [NH_3]^2 )
  • Answer: C

18. If Kc > 1, then at equilibrium:

  • A) Reactants are favored
  • B) Products are favored
  • C) Neither reactants nor products are favored
  • D) Both are equal in concentration
  • Answer: B

19. If a system at equilibrium is disturbed, it will shift to:

  • A) Minimize the disturbance
  • B) Maximize reactants
  • C) Maximize products
  • D) Remain unaffected
  • Answer: A

20. For a given reaction, if the concentration of reactants increases, the equilibrium will:

  • A) Shift to the right
  • B) Shift to the left
  • C) Remain unchanged
  • D) Reach a new equilibrium
  • Answer: A