11. The First Law of Thermodynamics is a statement of the principle of:

  • A) Conservation of mass
  • B) Conservation of energy
  • C) Conservation of momentum
  • D) Conservation of charge
  • Answer: B

12. Which of the following equations represents the First Law of Thermodynamics?

  • A) ΔU = Q + W
  • B) ΔU = Q – W
  • C) ΔU = Q × W
  • D) ΔU = Q/W
  • Answer: B

13. In the First Law of Thermodynamics, ‘Q’ represents:

  • A) Work done
  • B) Heat transfer
  • C) Change in internal energy
  • D) Entropy change
  • Answer: B

14. If the work done by the system is positive, it indicates that:

  • A) Work is done on the system
  • B) The system is losing energy
  • C) The system is gaining energy
  • D) Work is done by the system on the surroundings
  • Answer: D

15. Which of the following processes is isothermal?

  • A) Heating of a gas at constant pressure
  • B) Compression of a gas at constant temperature
  • C) Expansion of a gas at constant volume
  • D) Heating of a gas without any heat loss
  • Answer: B

16. Hess’s Law states that:

  • A) The total enthalpy change of a reaction is the sum of the enthalpy changes of individual steps
  • B) Energy cannot be created or destroyed
  • C) The enthalpy change depends on the pathway taken
  • D) The heat of formation is always negative
  • Answer: A

17. In an adiabatic process, which of the following is true?

  • A) Heat is exchanged with the surroundings
  • B) The system remains at constant temperature
  • C) No heat is exchanged with the surroundings
  • D) The internal energy remains constant
  • Answer: C

18. If a gas expands in a piston and does 100 J of work while absorbing 50 J of heat, what is the change in internal energy?

  • A) -50 J
  • B) 50 J
  • C) 150 J
  • D) 100 J
  • Answer: B

19. When a chemical reaction occurs in a closed system, the heat absorbed or released is called:

  • A) Enthalpy
  • B) Entropy
  • C) Heat capacity
  • D) Specific heat
  • Answer: A

20. Which statement about enthalpy (H) is correct?

  • A) H is always negative
  • B) H is independent of temperature and pressure
  • C) H is a state function
  • D) H does not change during a phase transition
  • Answer: C