Chemistry

Electroanalytical Techniques: Conductometry, Potentiometry, and Voltammetry MCQs

Electroanalytical Techniques – Conductometry, Potentiometry, and Voltammetry MCQs

Electroanalytical techniques like Conductometry, Potentiometry, and Voltammetry are essential methods in analytical chemistry for measuring ionic conductivity, electrode potentials, and current responses. These techniques help in chemical analysis, solution characterization, and concentration determination of analytes. Learn how they work and their applications in modern electrochemistry.

Conductometry

  1. Conductometry measures:
    (a) Electrical resistance
    (b) Electrical conductivity of a solution
    (c) Light absorption
    (d) Thermal conductivity
    Answer: (b) Electrical conductivity of a solution
  2. The SI unit of conductivity is:
    (a) Ohm (Ω)
    (b) Siemens per meter (S/m)
    (c) Farad (F)
    (d) Volt (V)
    Answer: (b) Siemens per meter (S/m)
  3. Which type of reaction is commonly analyzed using conductometry?
    (a) Redox reactions
    (b) Precipitation reactions
    (c) Acid-base neutralization reactions
    (d) Complexometric reactions
    Answer: (c) Acid-base neutralization reactions
  4. Which factor affects the conductivity of a solution?
    (a) Temperature
    (b) Ion concentration
    (c) Type of electrolyte
    (d) All of the above
    Answer: (d) All of the above
  5. Which instrument is used to measure conductivity?
    (a) Conductometer
    (b) Spectrophotometer
    (c) Potentiometer
    (d) pH meter
    Answer: (a) Conductometer

Potentiometry

  1. Potentiometry measures:
    (a) Conductance
    (b) Electromotive force (EMF) of an electrochemical cell
    (c) Heat transfer
    (d) Light absorbance
    Answer: (b) Electromotive force (EMF) of an electrochemical cell
  2. Which of the following is used as a reference electrode in potentiometry?
    (a) Hydrogen electrode
    (b) Silver-silver chloride electrode
    (c) Calomel electrode
    (d) All of the above
    Answer: (d) All of the above
  3. Potentiometry is commonly used to determine:
    (a) pH of a solution
    (b) Molecular weight of a compound
    (c) Conductivity
    (d) Refractive index
    Answer: (a) pH of a solution
  4. The working principle of a potentiometer is based on:
    (a) Ohm’s law
    (b) Nernst equation
    (c) Beer-Lambert law
    (d) Hess’s law
    Answer: (b) Nernst equation

Voltammetry

  1. Voltammetry measures:
    (a) Absorbance of light
    (b) Electrical current as a function of applied potential
    (c) Heat change in a reaction
    (d) Conductivity of a solution
    Answer: (b) Electrical current as a function of applied potential
  2. Which electrode is commonly used as the working electrode in voltammetry?
    (a) Silver-silver chloride electrode
    (b) Platinum electrode
    (c) Mercury drop electrode
    (d) All of the above
    Answer: (d) All of the above
  3. Which type of voltammetry uses a dropping mercury electrode?
    (a) Cyclic voltammetry
    (b) Differential pulse voltammetry
    (c) Polarography
    (d) Amperometry
    Answer: (c) Polarography
  4. The peak current in voltammetry is proportional to:
    (a) Temperature of the solution
    (b) Concentration of the analyte
    (c) Pressure of the gas
    (d) Ionic strength of the solution
    Answer: (b) Concentration of the analyte
Kamran Fateh

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Kamran Fateh

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